Is “Photoionization” a Scrabble word?

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Yes
PHOTOIONIZATION
Valid in at least one Scrabble dictionary

Valid in these dictionaries

SOWPODS / CSW
Scrabble UK & International
Valid
TWL / NWL
Scrabble North America
Valid
Large English Dictionary
General English word list
Invalid

Meaning of Photoionization

noun
  1. 1.The ejection of electrons from an atom or other species following the absorption of photons.