Is “Complementation” a Scrabble word?

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Yes
COMPLEMENTATION
Valid in at least one Scrabble dictionary

Valid in these dictionaries

SOWPODS / CSW
Scrabble UK & International
Valid
TWL / NWL
Scrabble North America
Valid
Large English Dictionary
General English word list
Unavailable

Meaning of Complementation

noun
  1. 1.The replacement of a set by its complement

  2. 2.The interaction between two genetic units such that an organism can function normally if either one is defective

  3. 3.(grammar) The relationship of a phrase to its predicate