Is “Azo” a Scrabble word?

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Yes
AZO
Valid in at least one Scrabble dictionary

Valid in these dictionaries

SOWPODS / CSW
Scrabble UK & International
Valid
TWL / NWL
Scrabble North America
Valid
Large English Dictionary
General English word list
Valid

Meaning of Azo

adjective
  1. 1.Azote, nitrogen

  2. 2.Applied loosely to compounds having nitrogen variously combined, as in cyanides, nitrates, etc.

  3. 3.Now especially applied to compounds containing a two atom nitrogen group (-N=N-) uniting two hydrocarbon radicals, as in azobenzene etc.